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Creators/Authors contains: "Ovtcharova, Maria"

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  1. Abstract U-Pb geochronology by isotope dilution–thermal ionization mass spectrometry (ID-TIMS) has the potential to be the most precise and accurate of the deep time chronometers, especially when applied to high-U minerals such as zircon. Continued analytical improvements have made this technique capable of regularly achieving better than 0.1% precision and accuracy of dates from commonly occurring high-U minerals across a wide range of geological ages and settings. To help maximize the long-term utility of published results, we present and discuss some recommendations for reporting ID-TIMS U-Pb geochronological data and associated metadata in accordance with accepted principles of data management. Further, given that the accuracy of reported ages typically depends on the interpretation applied to a set of individual dates, we discuss strategies for data interpretation. We anticipate that this paper will serve as an instructive guide for geologists who are publishing ID-TIMS U-Pb data, for laboratories generating the data, the wider geoscience community who use such data, and also editors of journals who wish to be informed about community standards. Combined, our recommendations should increase the utility, veracity, versatility, and “half-life” of ID-TIMS U-Pb geochronological data. 
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  2. null (Ed.)
    Age determination of minerals using the U–Pb technique is widely used to quantify time in Earth's history. A number of geochronology laboratories produce the highest precision U–Pb dates employing the EARTHTIME 202 Pb– 205 Pb– 233 U– 235 U tracer solution for isotope dilution, and the EARTHTIME ET100 and ET2000 solutions for system calibration and laboratory intercalibration. Here, we report ET100 and ET2000 solution data from the geochronology laboratory of University of Geneva obtained between 2008 and 2021 and compare the most recent data with results from the geochronology laboratories of Princeton University and ETH Zürich. This compilation demonstrates that (i) the choice of the thermal ionization mass spectrometer model has no influence on precision and accuracy of the data; (ii) the often observed excess scatter of apparent ET100 solution 206 Pb/ 238 U dates can be mitigated by more careful tracer-sample equilibration; and (iii) natural zircon reference materials are not suitable for evaluating intra-laboratory repeatability and inter-laboratory reproducibility, since they combine several phenomena of natural system complexities (especially domains of different age within the same zircon grain, and residual loss of radiogenic lead in domains of high decay damage after chemical abrasion pre-treatment). We provide our best estimates of apparent dates for the ET100 solution ( 206 Pb/ 238 U date, 100.173 ± 0.003 Ma), for ET2000 solution ( 207 Pb/ 206 Pb date, 1999.935 ± 0.063 Ma), as well as for natural reference zircon Temora-2 ( 206 Pb/ 238 U date, 417.353 ± 0.052 Ma). These data will allow U–Pb laboratories to evaluate their analytical performance and to independently calibrate non-EARTHTIME tracer solutions in use. 
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